In our research we explore the
biogeochemical processes occurring at the soil-water-plant interface
(ak.a. the Rhizosphere) and how these processes influence the
mobility and bioavailability of trace nutrient elements and heavy metals in natural
systems. Metals enter the environment from a variety of sources,
whether geogenically from metal rich parent materials, or
anthropogenically from sources such as metal smelting/refining,
military training activities, land application of drinking water or
wastewater treatment residues or animal waste applications.
Understanding how these metals interact with the numerous inorganic,
organic and biological components present within soil is essential
to predicting their overall fate and impact on or within the
surrounding ecosystem. The intimate association between all
of these components makes it difficult to evaluate the chemical and
physical processes taking place with just one technique.
Therefore, I apply both macroscopic (e.g. stirred-flow dissolution,
sequential extraction) and microscopic (SEM, TEM, confocal
microscopy) and molecular (XAS) techniques to
explore the multiple scales over which these processes are
occurring. One of the most innovative techniques is
synchrotron based X-ray absorption spectroscopy (XAS). With cutting-edge focusing optics, the X-rays
produced at synchrotron facilities can be used to probe metal
distributions, correlations and speciation within heterogeneous
systems such as soils and plants, in-situ (i.e. with water).
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