Notes
Slide Show
Outline
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Farming Algal Fuel
An Aquaculture Production Perspective
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“Growing Fuel”
  • National Geographic
  • October 2007
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Why?
Fuel > $4.00/gal
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Exponential Increases
  • Population:  from 3 to 6.8 billion (1960-2010)
  • Fossil fuel consumption
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 U.S. Energy Shortage
  • Declining world oil reserves
  • US dependence on Foreign Oil
  • Limited US oil reserves
  • Concerns about global CO2
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Oil Reserves & Global Consumption
  • Proved World Reserves = 1.1-1.3 trillion barrels (DOE, 2007 & 2009)
  • Global Oil Consumption = 85 million barrels/day (DOE, 2006)
  • Proved US Oil Reserves = 21 billion barrels (DOE, 2007)
  • US Oil Consumption = 7.55 billion barrels/year (DOE, 2006 & 2007)
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Duration of Oil Reserves
  • Proved World Reserves = 1.2 trillion barrels
  • Global Oil Consumption = 85 million barrels/day
  • Proved World Supply = ~ 36 years (beginning in 2009)
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Algal Fuel Not Currently a “Commercial” Reality
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Current Production
  • Nutrition/nutraceuticals
  • Estimated 10,000 tons/year (photosynthetically)
  • Spirulina, Chlorella, Dunaliela, Haematococcus
  • Half in China
  • Remainder in Japan, Taiwan, USA, Australia & India
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Spirulina (A. platensis)
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Dunaliela salina
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Chlorella vulgaris
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Haematococcus pluvialis
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Other Production
  • As live aquaculture feeds (shrimp, bivalves, rotifers, etc.)
  • Dark fermentation: starch & sugar vs. light (Martek omega-3 lipids, KY)
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Production Systems
  • Photobioreactors – small scale & more prevalent (academic & government labs)
  • Ponds – large scale (98%)
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Spherical Photobioreactors
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Tubular Photobioreactors
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Aquatic Species Program
NREL, Artist’s Rendition (1987)
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Raceway & Circular Ponds
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Dunaliella Ponds
Australia
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Fuels from Algae
  • Hydrogen -- no plausible commercial method demonstrated
  • Methane -- wastewater treatment
  • Oil/biodiesel -- triglycerides/lipids
  • Ethanol -- starch/sugar
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Algal Strain Selection
  • * High lipid/oil content
  • * Maximum biomass/productivity
  • * Ease of harvest
  • monoculture - resist contamination
  • Tolerate environment (local conditions, water quality, high O2 & temp, etc.)
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Basic Resources Needed
  • Available water
  • Suitable pond topography (flat)
  • Clay soil
  • Source of CO2 enrichment
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Production
  • Starter cultures (1-2% biomass) in photobioreactors
  • Starter to seed intermediate pond/raceway, or
  • Large ponds (one to many hectares)
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Harvest
  • 20-40% of volume daily
  • Concentrate approx. 30-fold
  • Must be low cost
  • Remove from water column (“bio-flocculation” – clumping) with minimal chemicals
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Oil Removal
  • Cell disruption to extract
  • Solvents
  • Mechanical Separation
  • Further processing
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Problems
  • Single cell starter – genetic drift
  • Maintaining oil content
  • Invasive algal species (esp. ponds)
  • Grazers -- fungii, protozoa, rotifers, zooplankton
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Advantages
  • Algal generation times (hr-d)
  • Terrestrial plants (mo-yr)
  • More amenable to selection/GMOs
  • Use soybeans and corn for food
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CO2 Removal/Abatement
  • Combine with power plants
  • Flue CO2 removal
  • 5000-6000 acres of ponds for 500-megawatt power plant
  • Energy in vs. CO2 removed (& energy out)
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Economics
  • Need low capital & operating costs
  • Spirulina costs: $5K/ton
  • Equivalent for 25% oil: $20K/ton
  • 20-30 x higher than vegetable oil
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Systems Costs
  • Large scale systems costly (resources and infrastructure)
  • Availability of resources – e.g. free source of CO2
  • Overall open pond costs > $40K/ac
  • Univ. of KY researchers estimate $18-$30/gal oil -- before processing
  • Photobioreactors too costly: like RAS (recirculating systems)
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Estimated Production
  • 25% useable triglycerides
  • Overall open pond costs > $40K/ac
  • Annual yield = 1.5 K gal/ac
  • Fuel @ $4.00/gal won’t cover costs (capital, operating, et. al.)


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Terrestrial Biofuels

  • Ethanol – sugars/starch
  • Bio-diesel – oils/triglycerides
  • Higher plants more cost effective @ $100/barrel for crude oil


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R&D Challenges
  • Greater biomass
  • Higher oil content
  • Fast growth
  • Better methods for concentrating and harvesting
  • Cost effective systems
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Environmental Limits
  • Water
  • Light
  • CO2
  • pH swings/nutrients
  • Temperature


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Wastewater  Pond
(oxidation)
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Combined Objectives
  • Wastewater treatment/mgt
  • Bio-fuel production
  • By-product harvest (e.g. feed additives)
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Potential vs. Reality
  • Can we put a human on the moon? … Yes.
  • But, how much does it cost?
  • Business common sense:  final product value must exceed cost.
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References
  • Benemann, John. 2009.  Algae biofuels -- a brief introduction.   jbenemann@aol.com
  • Sheehan et. al.  1998.  U.S. Department of Energy's Aquatic Species Program: Biodiesel from Algae; Close-Out Report. 325 pp.; NREL Report No. TP-580-24190 http://www.nrel.gov/docs/legosti/fy98/24190.pdf
  • http://www.spe.org/spe-site/spe/spe/industry/reserves/GlossaryPetroleumReserves-ResourcesDefinitions_2005.pdf
  • US Department of Energy (DOE):
  • http://www.eia.doe.gov/emeu/international/reserves.html
  • http://www.eia.doe.gov/basics/quickoil.html
  • http://tonto.eia.doe.gov/dnav/pet/pet_cons_psup_dc_nus_mbbl_a.htm



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On-Line Literature
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